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Creators/Authors contains: "Schmitz, Mark_D"

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  1. Abstract Interpreting the paleomagnetic records of altered rocks, especially those from Earth's earliest history, is complicated by metamorphic overprints and recrystallization of ferromagnetic minerals. However, these records may be as valuable as a primary signal if the timing and mechanism of alteration‐related remagnetizations can be ascertained. We illustrate the success of this approach in the case of seafloor hydrothermal alteration by integrating simple rock magnetic and magnetic microscopy data with petrography, hyperspectral imagery, aeromagnetic surveys, field mapping, and geochronology of Paleoarchean basalts from North Pole Dome located in the East Pilbara Craton, Western Australia. We identify 12 hydrothermal episodes during the deposition of the stratigraphy between ∼3490 and 3350 Ma. These episodes produced stratabound zones of hydrothermal alteration with predictable facies successions of mineral assemblages reflecting sub‐seafloor gradients in fluid temperature, pH, composition, and water/rock ratios. Rock magnetic data and magnetic microscopy pinpoint the secondary ferromagnetic minerals within each alteration assemblage, revealing a specific single‐domain magnetite population within leucoxenes (titanite and anatase after primary titanomagnetites) that always accompanies low‐water/rock alteration in fluids buffered to pH equilibrium with the host basalts. Highly uniform magnetic properties indicate that once formed, these magnetites remain unchanged upon further exposure to rock buffered fluids, stabilizing them against later alteration events and making them durable paleofield recorders. The altered basalts hosting this magnetite have unique and consistent appearances, mineralogy, IR absorption features, aeromagnetic signatures, and magnetic properties across all hydrothermal systems studied here, highlighting how integrating these data sets can identify and interpret this alteration style in future paleomagnetic investigations. 
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  2. Garnet U‐Pb dating by laser ablation‐inductively coupled plasma‐mass spectrometry requires the development of matrix‐matched reference materials of variable chemistry and U mass fraction for accurate analysis. Additional calibration of existing primary reference materials is also justified based on the relatively poor calibration of some of the widely available primary reference materials that are currently utilised by the geoscience community. We present a micro sampling workflow combined with a refined ID‐TIMS methodology for the generation of high precision (~ 0.1%) U‐Pb dates from domains within garnet single crystals. Using this workflow, we calibrated two new natural andradite reference materials, the Jumbo andradite (And99; 110.34 ± 0.03 (0.04) [0.13] Ma,n= 7, MSWD = 1.21) and the Tiptop andradite (And87; 209.57 ± 0.11 (0.13) [0.26] Ma,n= 6, MSWD = 1.39). We also present additional calibration of the widely utilised Willsboro‐Lewis andradite primary reference material (And90; 1024.7 ± 9.5 (9.6) [9.6] Ma (2s; overdispersed),n= 6). Wafers of the Jumbo and Tiptop andradite reference materials are available from the authors upon request. 
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  3. Abstract Mafic intrusions, lava flows, and felsic plutons in southwestern Laurentia have been hypothesized to be associated with the emplacement of a late Mesoproterozoic (Stenian Period) large igneous province. Improved geochronologic data resolve distinct episodes of mafic magmatism in the region. The ca. 1,098 Ma main pulse of southwestern Laurentia large igneous province (SWLLIP) magmatism is recorded by mafic intrusions across southeastern California to central Arizona. A younger episode of volcanism resulted in eruptions that formed the ca. 1,082 Ma Cardenas Basalt, which is the uppermost unit of the Unkar Group in the Grand Canyon. With the updated geochronological constraints, we develop new paleomagnetic data from mafic sills in the SWLLIP. Overlapping poles between the Death Valley sills and rocks of similar age in the Midcontinent Rift are inconsistent with large‐scale Cenozoic vertical axis rotations in Death Valley. We also develop a new paleomagnetic pole from the ca. 1,082 Ma Cardenas Basalt (pole longitude = 183.9°E, pole latitude = 15.9°N,  = 7.4°,N = 18). The new paleomagnetic data are consistent with the pole path developed from time‐equivalent rocks of the Midcontinent Rift, supporting interpretations that changing pole positions are the result of rapid equatorward motion. These data add to the record of Laurentia's rapid motion from ca. 1,110 to 1,080 Ma that culminated in collisional Grenvillian orogenesis and the assembly of Rodinia. 
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